Modern Problems of Materials Science

Features of Chronoamperometric Studies of Water Sorbent Materials

Keywords

MH electrode, сonstant potential discharge, hydrogen diffusion coefficient

Abstract

The present study examines the constant potential discharge method at –0.6 V (CPD) for three different hydrogen absorbing materials: nano-Ni-C synthesized from polystyrene and metal salts using the pyrolysis method; Ni-Raney obtained through leaching, and La3MgNi14 alloy are prepared by sintering and prolonged heat treatment. Each of the samples corresponds to distinct time domains (according to the theory of the method under consideration), indicating different mechanisms diffusion and hydrogen diffusion coefficients.

References

  1. Feng F. and Northwood D.O. Hydrogen diffusion in the anode of Ni/MH secondary batteries // J. Power Sources. – 2004. – 136. – P. 346-350. https://doi.org/10.1016/j.jpowsour.2004.03.015
  2. Khaldi C., Mathlouthi H., Lamloumi J. and Percheron-Guegan A. Electrochemical study of cobalt-free AB5-type hydrogen storage alloys // Int. J. Hydrog. Energy. – 2004. – 29. – P. 307-311. https://doi.org/10.1016/S0360-3199(03)00157-5
  3. Vlad Kh.I., Verbovytskyi Yu.V., Bogatyrov V.M. and Zavaliy I.Yu. // J. Mater. Sci. – 2022. – №. 6. – P. 96-102
  4. Zheng G. Electrochemical Determination of the Diffusion Coefficient of Hydrogen Through an LaNi4.25Al0.75 Electrode in Alkaline Aqueous Solution // J. Electrochem. Soc. – 1995. – 142. – P. 2695-2698. https://doi.org/10.1149/1.2050076
  5. Hosni B., Khaldi C., ElKedim O., Fenineche N. and Lamloumi J. Electrochemical properties of Ti2Ni hydrogen storage alloy // Int. J. Hydrog. Energy. – 2017. – 42. – P. 1420-1428. https://doi.org/10.1016/j.ijhydene.2016.04.032
  6. Dymek M., Nowak M., Jurczyk M. and Bala H. Electrochemical behavior of a nanostructured La1.25Gd0.25Mg0.5Ni7 hydrogen storage material modified with magnetron sputtered nickel // J. Electrochem. Soc. – 2019. – 166. – P. A1393-A1399. https://doi.org/10.1149/2.0391908jes