Modern Problems of Materials Science

Synthesis, Structure and Electrochemical Properties of the NdY2Ni9-xMnx Alloys

Keywords

Rare-earths alloys, Ni-MH batteries, electrochemical hydrogenation properties

Abstract

This paper presents the results of investigation of energy-efficient materials for Ni-MH batteries based on Ni substitution by Mn in the NdY2Ni9 alloys. Synthesized using arc melting and annealing, the alloys crystallize in a LaY2Ni9 type of structure. Electrochemical studies reveal nonlinear effects of Mn substitution on discharge capacity. The highest discharge capacity was found for the NdY2Ni8Mn alloy with 352 mAh/g, retaining 73% capacity after 50 charge/discharge cycles.

References

  1. Wan C., Denys R. and Yartys V. Effect of yttrium content in the La2-xYxMgNi 9 battery anode alloys on the structural, hydrogen storage and electrochemical properties // Dalton Trans. – 2022. – 51 – P. 12986-12995. https://doi.org/10.1039/D2DT01957D
  2. Latroche M., Paul-Boncour V., and Percheron-Guégan A. Structural properties of two deuterides LaY2Ni9D12.8 and CeY2Ni9D7.7 determined by neutron powder diffraction and X-ray absorption spectroscopy. // J. Solid State Chem. – 2004. – 177, № 7. – P. 2542-2549. https://doi.org/10.1016/j.jssc.2004.03.034
  3. Berezovets V., Denys R. and Zavaliy I. Crystal structure and thermodynamic properties of YNi2.67Mn0.33H4 hydride // Visnyk Lviv Univ. Ser. Chem. – 2008. – 49, №1. – P. 121-127.
  4. Verbovytskyy Y., Oprysk V., Lyutyy P., and Zavaliy I. Electrochemical hydrogenation properties of new YNi3 and YNi4 based alloys // Solid State Phenom. – 2022. – 331 – P. 25-30. https://doi.org/10.4028/p-c9wr6y